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Affiliation(s)

Department of Informatics and Environmental Sciences, Kyoto Prefectural University, 1-5, Shimogamo Nakaragi-cyo, Sakyo-ku, Kyoto 606-8522, Japan

ABSTRACT

Novel phosphate pigments imitated with Scorzalite, FeAl2(PO4)2(OH)2, were prepared from iron and aluminum nitrate solutions, ascorbic acid, and phosphoric acid with pH adjustments (pH 5, 7, 9). The obtained precipitates were heated at 300, 500, and 700 °C for 1 h. The precipitates and their thermal products were estimated with X-ray diffraction (XRD), Infrared (IR) spectra, ultraviolet-visible (UV-Vis) reflectance spectra, and L*a*b* color space. The precipitated sample was not clearly colored, but it turned orange to red when heated. Samples prepared at low pH showed higher whiteness than samples prepared at high pH. The theoretical amount of ascorbic acid was sufficient to completely reduce iron during the adjustment. This study showed the possibility of novel inorganic phosphate red pigment.

KEYWORDS

Iron aluminum phosphate, natural ore, red pigment.

Cite this paper

Journal of Materials Science and Engineering A 11 (4-6) (2021) 35-39

References

[1] Amat, A., Millani, C., and Fantacci, S. 2016. “Structural and Electronic Properties of the PbCrO4 Chrome Yellow Pigment and of Its Light Sensitive Sulfate-Substituted Compounds.RSC Adv. 6: 36336-44.

[2] Tao, Z., Zhang, W., Huang, Y., Wei, D., and Seo, H. J. 2014. “A Novel Pyrophosphate BaCr2(P2O7)2 as    Green Pigment with High NIR Solar Reflectance     and Durable Chemically Stability.Solid State Sci. 34: 78-84.

[3] Radepont, M., Conquinot, Y., Janssens, K., Ezrati, J.-J., and Cotte, M. 2015. “Thermodynamic and Experimental Study on the Degradation of the Red Pigment Mercury Sulfide. J. Anal. At. Spectrom. 30: 599-612.

[4] Rosi, F., Grazia, C., Gabrieli, F., Romani, A., Paolantoni, M., Vivani, R., Brunetti, B. G., Colomban, P., and Miliani, C. 2016. “UV-Vis-NIR and Micro Raman Spectroscopies for the Non Destructive Identification of Cd1-xZnxS Solid Solutions in Cadmium Yellow Pigments.Microchem. J. 124: 856-67.

[5] Li, M., Wand, J., and Ma, Q. 2015. “The Effect of Lead Additives on Ancient Chinese Purple Pigment Synthesis.” J. Cultural Heritage 16 (4): 575-8.

[6] Jiang, S., Peng, L., Guo, R., Miao, D., Shang, S., Xu, J., and Li, A. 2016. “Preparation and Characterization of Fe2O3 Coating on Quarts Fabric by Electron Beam Evaporation. Ceram. Intern. 42 (16): 19386-92.

[7] Migurei, C., Pinto, J. V., Clarke, M., and Melo, M. J. 2014. “The Alchemy of Red Mercury Sulphide: The Production of Vermillion for Medieval Art.Dyes Pig. 102: 210-7.

[8] Ohashi, M., Kusumoto, K., Sugiyama, T., and Kato, K. 2016. “Influence of Nitrides on Synthesis of Tantalum (V) Oxynitride TaON by Heat Treatment without Flowing Ammonia.J. Ceram. Soc. Jpn. 124 (9): 959-62.

[9] Cejka, J., Sejkora, J., Macek, I., Malíková, R., Wang, L., Scholz, R., Xi, Y., and Frost, R. L. 2015. “Raman and Infrared Spectroscopic Study of Turquoise Minerals.Spectrochim. Acta 149: 173-82.

[10] Othmane, G., Hull, S., Fayek, M., Rouxel, O., Geagea, M. L., and Kyser, T. K. 2015. “Hydrogen and Copper Isotope Analysis of Turquoise by SIMS: Calibration and Matrix Effects.Chem. Geol. 395: 41-9.

[11] Onoda, H., and Sasaki, R. 2019. “Synthesis of Novel Phosphate Pigments in Imitation of Turquoise.Materials Res. Innov. 23 (5): 266-9.

[12] Onoda, H., and Sasaki, R. 2019. “Preparation of Novel Blue Phosphate Pigments in Imitation of Turquoise.Cerâmica 65 (376): 641-4.

[13] Kumari, L. S., Rao, P. P., Radhakrishnan, A. N. P., James, V., Sameera, S., and Koshy, P. 2013. “Brilliant Yellow Color and Enhanced NIR Reflectance of Monoclinic BiVO4 through Distortion in VO43- Tetrahedral.Sol. Energy Mater. Sol. Cells 112: 134-43.

[14] Onoda, H., and Sugimoto, K. 2017. “Synthesis of Novel Green Phosphate Pigments in Imitation of Natural Ores.” J. Asian Ceram. Soc. 5 (2): 123-6.

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