Affiliation(s)
1. Department of Soil, University of Viçosa, Av. Peter Henry Rolfs, Bulding Silvyo Starling Brandão, CEP 36570-000, Viçosa (MG), Brazil
2. Department of Chemistry, University of Viçosa, Rio Paranaíba Campus, Highway MG-230, KM 07, CEP 38810-000, Rio Paranaíba (MG), Brazil
3. Department of Fundamental Chemistry, University of São Paulo, Av. Prof. Lineu Prestes, 748, CEP 05508-000, São Paulo (SP), Brazil
ABSTRACT
With demand increasing for phosphate recovery, a considerable share of
current research is dedicated to elaborate multifunctional materials. In this
way, the objective of this work was to produce hybrid films from the
combination of cellulose acetate (CA) biopolymer and magnesium and
aluminium layered double hydroxides (LDHs) and investigate their performance
for phosphate recovery. In this work, the following materials were prepared and
characterized: LDH, calcinated LDH (LDH-c), CA film (CAF), CA film with LDH
(CAF-LDH) and CA film with LDH-c (CAF-LDH-c). The produced materials were
characterized by X-ray diffraction, thermogravimetric analysis coupled with
differential scanning calorimetry and mass spectrometry, attenuated total reflectance Fourier transform infrared spectroscopy
and scanning electronic microscopy. The thickness, H2O
absorption (AH2O), stability in H2O
and phosphate adsorption of the produced films were evaluated. The adsorption
capacity of films was compared to LDHs in powder form. The CAF-LDH and
CAF-LDH-c increased film thickness, where CAF-LDH-c was thicker than CAF-LDH.
CAF-LDH-c had higherAH2O than the other films, because of
its increased thickness and mainly because of the H2O sorption
process of these materials. H2O stability of 98.97% for CAF-LDH and
96.81% for CAF-LDH-c suggest the produced films can maintain their structural
properties even after a long contact period with aqueous solutions. For the
CAF-LDH-c, the maximum adsorption capacity of phosphate, according to the Langmuir-Freundlich
model, was 6.98 mg/g. The adsorption
value suggests that this film can be used as an efficient phosphorus (P)
adsorbent from wastewater or a eutrophicated source.
KEYWORDS
Cellulose acetate films, layered double hydroxides, phosphorous adsorption,
phosphorous recovery.
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