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Kinetic Model Heterogeneous Reaction Self-assembly on Nanocomposit Sorbent and Their Peculiarity
Kibalnikova Olga V.
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DOI:10.17265/1934-7375/2018.03.007
Kinetic modeling of self-assembly reactions occurring on a nanocomposite with the formation of dimers in a solvent cell and molecular complexes in micelles is presented. In this self-organization occurs due to the synergistic effect, due to a combination of nonvalent interactions. This approach opens up new possibilities in the field of chromatographic and separation technologies related to the analysis of complex mixtures. The coefficient α of the self-assembling processes at the nanocomposite. It is shown that α can have different values, for example, for pyridine dimer in cage solvent this coefficient is 2.5~3.4. Quantum chemical calculations show that the surface of the nanocomposite is doped with alkaline metal, which restores hydrogen atoms, turning them into H-. This is used in a chromate-mass spectrometer in identify environmental toxicants, the technique of determining metaphase in food products.
Self-assembly reaction, nanocomposit, equation N.I. Brensted, intercaljacia, chromate-mass-spectrometrija, metaphos, helium.
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