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Affiliation(s)

1. Graduation School of Science and Technology, Niigata University, Niigata 950-2181, Japan
2. Department of Chemistry and Chemical Engineering, Faculty of Engineering, Niigata University, Niigata 950-2181, Japan

ABSTRACT

In this paper, the adsorbent for the removal of hexavalent Cr (Chromium) from aqueous solutions has been prepared by modifying chitosan composite with EP (Epichlorohydrin) or GA (Glutaraldehyde). The modified cross-linked chitosan was characterized by SEM (Scanning Electron Microscopy) and FT-IR (Fourier Transform Infrared Spectroscopy). Batch adsorption experiments were carried out to evaluate the adsorption of Cr(VI) by the cross-linked chitosan under different conditions. Furthermore, the sorption mechanism of Cr(VI) by the cross-linked chitosan was investigated by applying Langmuir and Freundlich isotherm equations to the data obtained. The concentration of Cr in solution was determined by ICP-MS (Inductively Coupled Plasma Mass Spectrometry). The cross-linked chitosan can be an efficient sorbent for Cr(VI).

KEYWORDS

Cross-linked chitosan, EP (Epichlorohydrin), GA (Glutaraldehyde), hexavalent Cr (Chromium), adsorption isotherms, kinetics.

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